Product ID:SODIUM SULFIDE
MSDS Date:01/01/1987
FSC:6750
NIIN:00-200-2403
MSDS Number: BDJFQ

PPG INDUSTRIES,INC.

1 PPG PL
PITTSBURGH, PA 15272
US

Emergency Phone: NONE

Cage: GO796

PPG INDUSTRIES,INC. COATINGS TRESINS DIV.

PITTSBURGH, PA 15272 US

Telephone: 1-800-245-2974 (CAL HYPO)

Cage: GO796

SODIUM SULFIDE,NA*2S.(WITH 38.0% WTR OF CRYSTALLIZATION).

RTECS: WE1910000

SODIUM HYDROSULFIDE,NAHS

RTECS: WB4800000

SODIUM HYDROXIDE (SARA III)

CAS: 1310-73-2

RTECS: WB4900000

OSHA PEL 2 MG/M3

ACGIH TLV: C 2 MG/M3; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

SODIUM THIOSULFATE,NA*2S*2O*3

CAS: 7772-98-7

RTECS: XN6476000

CARBON DIOXIDE

CAS: 124-38-9

RTECS: FF6400000

OSHA PEL 5000 PPM

ACGIH TLV: 5000PPM/30000STEL;93

Effects of
Overexposure:EYE/SKIN:CORROSIVE,IRRITATING,BURNING-INGESTION:CORROS
IVE,BURNING,INHALATION:BURNING.

First Aid:INHAL:RMV TO FRESH AIR. IF NOT BRTHNG GIVE CPR; IF BRTHNG
DIFF GIVE OXYGEN. EYE:IMMED FLUSH W/PLENTY OF WATER. SKIN:WASH
W/SOAP & WATER. RMV CONTAM CLTHG & SHOES. INGEST:DO NOT INDUCE
VOMIT. NOTHG BY MOUTH IF UNCONSC. GET MEDICAL ATTN.

Flash Point:NON-FLAMMABLE
Fire Fighting Procedures:NIOSH/MSHA-APPROVED SCBA IN THE PRESS.DEMAND
MODE.
Unusual Fire/Explosion Hazard:CONTACT W ACIDS WILL LIBERATE
POISONOUS,FLAMMABLE HYDROGEN SULFIDE GAS.

Spill Release
Procedures:IMM.EVACUAT.AREA,REMOV.IGN.SOURCES,PROVID.MAX.VENTILTN.O
NLY PERSONNL EQUIPPED W SCBA AND EYE/SKIN PROTECTN,ALLOWD IN
AREA.SWEEP SPILLD MATL INTO CNTNRS FOR DISPOSL.RECLAIM IF
POSSIBL.THOROUGHLY WET VA CUUM AREA.DO NOT CONTCT W ACIDS.DONOT
FLUSH TO SWR

Handling and Storage Precautions:STR AWAY FROM OXIDIZING AGTS/DO NOT
CONTCT W/ACIDS.STR IN COOL,VENTLTD AREA/WEAR SCBA WHEN EXPOSURE IS
LIKELY/DO NOT STR IN OPEN,UNLABLD CNTNRS.
Other Precautions:DO NOT STR IN ZN,AL OR CU CNTNRS/KEEP CNTNRS
CLSD/WEAR GOGGLS,RUBBER GLVS,APRON,BOOTS WHEN HANDLING/DO NOT
BREATH DUST/DO NOT GET IN EYE,SKIN/USE W ADEQUATE VENTLN/DO
EAT,DRINK,SMOKE IN AREA.

Respiratory Protection:COMB.ACID/GAS;DUST/MIST CARTRIDGE W FULL
FACEPIECE.
Ventilation:LOCAL EXHAUST
Protective Gloves:NEOPRENE
Eye Protection:CHEMICAL GOGGLES
Other Protective Equipment:BOOTS,APRON,CHEMICAL SUITS.
Supplemental Safety and Health
INCOMPAT:ATTACK ZN,CU,ALUMINUM & ALLOYS,MFR RECOMMNDS INSTALL
CONTINUOUS MONITORING HYDROGEN SULFIDE GAS DETECTN & ALARM SYSTEM
WHERE GENERATION OF SULFIDE GAS MAY OCCUR.MSDS DATED 6/83.

HCC:B1
Boiling Pt:=174.4C, 346.F
Spec Gravity:1.858
Solubility in Water:APPRECIABLE
Appearance and Odor:WHITE TO YELLOW FLAKES,SLIGHT ROTTEN EGG ODOR

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS AND ACIDS.SOD.SULF.SOLNS.-SEE SUPPL.
Stability Condition to Avoid:AVOID CONC.SOLNS.-COULD CAUSE SPONTANEOUS
IGNITION.
Hazardous Decomposition Products:CONTACT W ACIDS WILL LIBERATE
FLAMM,POISONOUS HYDROGEN SULF.

Waste Disposal Methods:MUST BE DISPOSED OF IN AN APPROVD WST MGMT
FACILITY.AVOID ENVIRONM.CONTAMINTN.DISPOSE OF IAW ALL LOCAL,STATE &
FDL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.